ABSTRACT: Studies regarding background concentrations of rare earth elements (REEs) are scarce and have mainly focused on a limited number of soil types from the northern hemisphere. The aim of this study was to determine REE concentrations in thirty-five benchmark soils of Brazil. Composite soil samples were taken from areas under native vegetation or with minimal anthropogenic influence. Concentrations of La, Ce, Pr, Nd, Sm, Eu, Gd, Yb, Lu, Dy, Er, Ho, Tb, Tm, Y, Sc, and Fe were determined […]

ABSTRACT: High growth rate is one of the criteria used for the selection of species to be used in metal phytoextraction programs. This study was carried out to characterize the growth characteristics of sunflower (Helianthus annuus L.), castor bean (Ricinus communis L.), corn (Zea mays L), and vetiver [Vetiveria zizanioides (L.) Nash] grown on a soil contaminated with lead (Pb), with and without pH correction, to improve agronomic practices regarding phytoremediation programs. The experiment was designed as a randomized block […]

ABSTRACT Revegetation is essential to improve the quality of constructed soils. This study investigated effects of perennial grasses on total organic carbon (TOC) stock, organic matter (OM) fractions and on quality of a recently constructed soil, after coal mining. Soil samples were collected from the 0.00-0.03 m layer two years after the beginning of the experiment. The treatments consisted of Cynodon dactylon cv vaquero (T1); Urochloa brizantha (T2); Panicum maximun (T3); Urochloa humidicola (T4); Hemarthria altissima (T5); Cynodon dactylon cv […]

ABSTRACT Bioavailability of heavy metals at contaminated sites is largely controlled by the physicochemical properties of the environmental media such as dissolved organic matter, hydroxides and clay colloids, pH, soil cation exchange capacity and oxidation-reduction potential. The aim of this study was to investigate soil pH and heavy metal solubility effect by levels of humic and fulvic acids applied in soil samples with different levels of contamination by heavy metals. The soil samples used in this study were collected in […]

ABSTRACT Soil contamination by heavy metals threatens ecosystems and human health. Environmental monitoring bodies need reference values for these contaminants to assess the impacts of anthropogenic activities on soil contamination. Quality reference values (QRVs) reflect the natural concentrations of heavy metals in soils without anthropic interference and must be regionally established. The aim of this study was to determine the natural concentrations and quality reference values for the metals Ag, Ba, Cd, Co, Cu, Cr, Mo, Ni, Pb, Sb and […]

ABSTRACT Heavy metals contained in electronic waste, if discarded improperly, can become bioavailable after vermicomposting, posing a risk to the environment. Small-scale vermicomposting experiments were carried out with printed circuit boards (PCBs) to investigate the migration of heavy metals (Cu, Pb, Zn, Ni, and Sn) to the final compost, as well as the mobility and bioavailability of these metals. High total levels of Pb, Sn and Cu in samples of manure with electronic waste (MEW) and vegetables with electronic waste […]

ABSTRACT The agricultural use of sewage sludge and derivatives is to be carried out according to requirements established by Brazilian federal legislation and by legislation of the State of São Paulo, which requires that these organic materials must have at least 30 % of the total organic carbon degraded when incorporated in agricultural soils. To observe the degradation rates of sewage sludge and of organic compost produced from the same sewage sludge mixed with ground material from tree pruning, we […]

ABSTRACT The disposal of large amounts of coal mining waste chemically modifies the soil, and this may change the structure and activity of soil fauna. The objective of this investigation was to study the ecotoxicological effects of depositions of pyritic waste (coal plus pyrite) in two soils collected in Santa Catarina, Argissolo Vermelho-Amarelo (Ultisol) e Nitossolo Háplico (Hapludox), at the application rates of 0, 2.5, 5, 10, and 20 % of that residue. Survival and reproduction of Enchytraeus crypticus and […]

ABSTRACT High contents of plant-available selenium in the soil in the form of selenate, resulting from natural or anthropogenic action, jeopardizes agricultural areas and requires research for solutions to establish or re-establish agricultural or livestock operation, avoiding the risk of poisoning of plants, animals and humans. The purpose was to evaluate sulfur sources in the form of sulfate, e.g., ammonium sulfate, calcium sulfate, ferric sulfate, in the remediation of tropical soils anthropogenically contaminated with Se under the tropical forage grass […]

ABSTRACT Soils rebuilt after coal strip mining is composed of topsoil and, or, overburden, and their chemical properties differ from those of natural soils mainly due to the sulfurization process. The objective of this study was to evaluate the potential for acidification from sulfides and heavy metal contamination across profiles of soils rebuilt after coal mining, in areas of different ages, with and without concomitant environmental reclamation during mine operations. Mining areas of different ages were selected: areas I and […]