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Fate of nickel ion in (II-III) hydroxysulphate green rust synthesized by precipitation and coprecipitation

Lucia Helena Garófalo Chaves, Joan Elizabeth Curry, David Andrew Stone, Jon Chorover

01/Aug/2007

In order to investigate the efficiency of sulfate green rust (GR2) to remove Ni from solution, GR2 samples were synthesized under controlled laboratory conditions. Some GR2 samples were synthesized from Fe(II) and Fe(III) sulfate salts by precipitation. Other samples were prepared by coprecipitation, of Ni(II), Fe(II) and Fe(III) sulfate salts, i.e., in the presence of Ni. In another sample, Ni(II) sulfate salt was added to pre-formed GR2. After an initial X-ray diffraction (XRD) characterization all samples were exposed to ambient […]